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I think it's the ammonia from the urine but I don't know if i would be in a hurry either to get the dog something to ingest to prevent that. If supplements will works then at least the dog will benefit. I'm just a bit weary of feeding him something to prevent brown lawn patches that might affect him in the short or long run. Just water the spot in the lawn and it should grow back pretty green and fine.
Pardon me for saying this but anything that dogs would ingest for that acidic urine might cause the dog damage in the long run. The dog's kidneys are weak and can easily be weakened by ingesting something that has no approved therapeutic claims. I agree that there are some hard chemical in the dog's urine but it can be rinsed off with water for the health of the grass. Please don't give the dog anything to soften the urine.