Spraying plants with Chlorantholanil (and some other types of fungicides) is like putting Armor-All on car tires. It puts a protective layer on the plant and leaves that fungi does not stick to so they don't attach and eat the plant when they land on the plants surface. Rain can wash that protection off of the plant so then fungi can then stick to the plant. Even it does not rain for awhile, fast growing plants (like vegetables) can also what I imagine is "stretch" the protection so there are gaps in the protective layer that fungi can then stick to and eat the plant so time between sprayings can be considered a variable.
This type of protection does not protect the plant from soil borne disease entering through the roots (vericillium, fusarium, southern blight, etc) and also does not protect the plant from every type of air borne fungi.