There's a great YouTube video about plastics. The scene opens up on a high class party, an older gentleman pulls aside an upcoming businessman and tells him outside, "When I tell you this one word, this one product is going to change the world. Plastic." Scene closes.
Plastics are a god send, they get a terrible wrap from the media and focus groups and a good chunk of plastics can be recycled. They are moldable to what ever you need, the applications can be as simple as a safe toy for children to an intense product in aerospace.
Glass is expensive to make and produce. To put them in a green house you need them to be tempered which adds a great deal of cost. When tempered glass becomes much stronger, and when it breaks it'll safely shatter to smaller pieces, which will cause less damage, if any at all, to what ever is below it.
To make glass you mix about 90% sand (silica) and other common minerals and throw them in to a fire bed at temperatures close to 600°c iirc, to temper glass it gets up to 1400°c and cools to 100° in about 5-10 minutes AFTER the glass is made.
Glass weighs more than plastics. Glass doesn't really filter light, if you can get it polorized you can cancel out certain wave lengths. Tints help filter wave lengths as well.
Plastics are extremely inexpensive compared to glass, an average of $1.66 can be applied to per sq.ft of plastic coverage on a 6mm twin panel of polycarbonate, where on tempered glass you're looking at $25/sq.ft.
Plastics are extremely durable, polycarbonate can withstand minor hail storms! You can add different compounds (like you can with glass) and change its chemical structure and make it even stronger, at an marginal increased cost, or just thicker for an cheaper increase.
Plastics are extremely light weight, I am ordering a 10'x10' 6mm twin wall polycarbonate and it weighs in at maybe 100# where a similar glass is maybe 300# so there's a MAJOR shipping's saving.
Plastics are naturally UV resistant and transmission of UV is about .01%, plants use the majority of the yellow spectrum for photosynthesis, so you won't get leaf burn with plastics - only down side is a lot of 'natural sterilization' is by UV light.
Plastic is more flexible than glass too, if. You're needing to bend it for what ever reason, just know you are creating a stress point which may break in the future.
My votes plastic. Hands down.
But if you got the money to blow, glass looks more... Classic? Elegant? Bragging rights?