I'm writing this with the assumption, that a "hotbox" is the same as a "Cold frame", just most aptly named ?
We recently had all our windows replaced (Original Edwardian wood-frame windows, 11 slash-windows, so 22 separate window panels) for better insulation, etc. I simply couldn't bear to just let them all go to the scrap yard, so I kept around 8 to make a row of cold-frames/hotboxes along my south-facing garden wall. (Made with old, weathered house-bricks from the outhouse I used to have in the garden). I love them, really proud of myself. hehe
I'll take photos when I find my camera.
The rest I gave away to friends, family, and finally on Freecycle to any locals who could make use of them. I knew they'd come in handy one day, the windows and the house-bricks; I seem to have a problem throwing anything away..
Obviously, these windows had no anti-UV coating on them, but I can't see that it will cause too much of a problem for your plants. If you find after you've planted under the windows, that your plants aren't growing as well as expected, and you have no other explanation, it might be worth a trip up the scrapyard to see if they have some old windows you could take off their hands instead? Don't forget to come back to tell us how you get on, as it's useful to know for future reference.